Physical Chemistry
Thermodynamics
 Edition:
 1st
 Author(s):
 Horia Metiu
 ISBN:
 9780815340911
 Format:
 Paperback
 Publication Date:
 February 21, 2006
 Content Details:
 318 pages
 Language:
 English
Related Titles
Also of Interest

About the Book
Book Summary
This is a new undergraduate textbook on physical chemistry by Horia Metiu published as four separate paperback volumes. These four volumes on physical chemistry combine a clear and thorough presentation of the theoretical and mathematical aspects of the subject with examples and applications drawn from current industrial and academic research. By using the computer to solve problems that include actual experimental data, the author is able to cover the subject matter at a practical level. The books closely integrate the theoretical chemistry being taught with industrial and laboratory practice. This approach enables the student to compare theoretical projections with experimental results, thereby providing a realistic grounding for future practicing chemists and engineers. Each volume of Physical Chemistry includes Mathematica® and Mathcad® Workbooks on CDROM.
Metiu's four separate volumesThermodynamics, Statistical Mechanics, Kinetics, and Quantum Mechanicsoffer builtin flexibility by allowing the subject to be covered in any order.
These textbooks can be used to teach physical chemistry without a computer, but the experience is enriched substantially for those students who do learn how to read and write Mathematica® or Mathcad® programs. A TI89 scientific calculator can be used to solve most of the exercises and problems.
® Mathematica is a registered trademark of Wolfram Research, Inc.
® Mathcad is a registered trademark of Mathsoft Engineering & Education, Inc.
Features
 Pedagogical approach; oversimplifications are removed, realistic examples are used, and extensive comparisons between experiments and theory are provided.
 Mathematica and Mathcad Workbooks on CDROM accompany each volume.
 Clear presentation and comprehensive coverage of topics.
 Builtin flexibility; the four separate volumes allow the subject to be covered in any order.
 The topical coverage is determined by the needs of the practical chemist.
 Original voice: Horia Metiu covers the subject matter with a fresh narrative style.
Reviews
"Metiu’s fourvolume text is an ambitious attempt to present the traditional, core areas of physical chemistry in a fresh way, using modern symbolic manipulation programs to perform many of the derivations and calculations. The endeavor deserves to succeed. I anticipate that the work will come to be seen as a yardstick against which other mainstream physical chemistry texts will be judged."  Chemistry World
"The scheme adopted by Metiu allows individual areas of physical chemistry to be treated in greater detail than would otherwise be possible... The work is overall to be welcomed, representing as it does an approach to the teaching of physical chemistry that in some respects differs radically from the customary one."  Prof. Ian R. McDonald, University of Cambridge, UK (review for Molecular Physics journal)
"I anticipate that the work will come to be seen as a yardstick against which other mainstream physical chemistry texts will be judged."  Prof. Mike Ashford, University of Bristol, UK (review for Chemistry World)
"Horia Metiu has created a significant set of volumes on undergraduate physical chemistry. The integration of Mathematica and Mathcad workbooks into the four texts provides instructors with an attractive new option in teaching. Metiua's writing style is folksy and the graphics minimal, a refreshing approach¦.Taken as a whole, the four volumes on physical chemistry by Metiu are impressive, particularly Thermodynamics and Quantum Mechanics¦.Without a doubt, the four textbooks provide essential materials of great utility to physical chemistry instructors. The bottom line is that the set of four volumes is a must havea keeper as a novel resource or invaluable classroom tool."  Journal of Chemical Education, February 2008, Vol. 85, No. 2, p. 206

Contents
1. Temperature, Pressure, Molar volume, Equilibrium
2. The Equation of State
3. How to Use the Equation of State
4. Thermodynamic Transformations
5. Work
6. Heat
7. Reversible and Irreversible Transformations
8. PathDependent and Pathindependent Quantities
9. First and Second Laws
10. Helmholtz and Gibbs Free Energies
11. How to Calculate the Change of Entropy in an Equilibrium Transformation
12. Enthalpy and Energy Change During a Thermodynamic Transformation
13. Thermochemistry
14. The Change of Chemical Potential During an Equilibrium Transformation
15. The Chemical Potential of a Compound in a Mixture
16. Mixtures: Partial Molar Quantities and Activities
17. Chemical Equilibrium
18. Chemical Equilibrium: The Connection Between the Equilibrium Constant and Composition
19. Chemical Equilibrium: How to Calculate the Equilibrium Constant from Delta G
20. Chemical Equilibrium: The Dependence of the Equilibrium Constant on Temperature and Pressure
21. Chemical Equilibrium of Coupled Reactions
22 Phase Transitions in OneComponent Systems: The Phenomena
23. Phase Transitions in OneComponent Systems: The Equilibrium Conditions
24. Phase Transitions in OneComponent Systems: How to Use the Equilibrium Conditions
25. Phase Equilibria in Binary Systems: The Phenomena
26. Equilibrium Conditions for Binary Systems with Two Phases: Application to VaporLiquid Equilibrum
27. Electrolyte Solutions
28. Electrochemistry: Phenomena
29. Electrochemistry: Equilibria
Appendices 1  9 
Student Resources
Student ResourcesWorkbooks using Mathematics and Mathcad.

Downloads
Samples & DownloadsClick on any of the links below to download a printable PDF of a sample chapter.
Chapter 2: The Equation of State